秦祖赠

更新时间:2024-07-31 22:17

秦祖赠,男,广西大学化学化工学院教授,专业方向是环境友好的催化过程。

个人经历

2009.10至今 广西大学,化学化工学院,讲师、副教授、教授

2015.10-2016.10 The University of Tennessee, Knoxville,Visiting scholar

2012.08-2015.03 中山大学,化学与化学工程学院,博士后

2004.09-2009.06:广西大学化学化工学院,化学工艺专业,获工学博士学位

2000.07-2004.08 广西桂林市红星化工总厂,工程师

1996.09-2000.06:广西大学化学化工学院,精细化工专业,工学学士

学术兼职 Springer-Nature旗下期刊Advanced Composites and Hybrid Materials编委

中国化工学会精细化工专业委员会青年委员

广西安全生产委员会专家

广西本科高校化工与制药类教学指导委员会秘书长

Reviewer for RSC, ACS, Springer, Wiley, and Elsevier (2010 - present): AIChE Journal, Chemical Engineering Journal, Materials Research Bulletin, Chemical Engineering Communication, Catalysis Communications, Nanoscale Research Letters, Industrial & Engineering Chemical Research, Journal of Harzardous Materials, Desalination and Water Treatment, Journal of the Air & Waste Management Association, etc.

中国人民政治协商会议第十三届广西壮族自治区委员会委员

主讲课程

本科生:

化学反应工程,化工分离工程,工业催化,制药反应工程,化工过程模拟与优化,生产实习,毕业实习,毕业论文

硕士生:

现代化工技术与进展,高等化工分离工程,高等反应工程(II),化工分子模拟

研究方向

Reaserch interesting:

1. Environmentally friendly catalytic process(环境友好的催化过程)

2. Separation and synthesis of fine chemicals, natural fine chemicals(精细化工、天然精细化学品的分离与合成)

科研项目

主持项目:

1.2019年国家自然科学基金地区基金,21968007,Ni基柱撑MXene的构筑、结构特征和催化肉桂醛加氢研究,2020.01-2023.12,40万,在研,主持.

2.2018年广西石化资源加工及过程强化技术重点实验室开放课题,2018K002,Ni 插层膨润土催化剂的制备及其催化CO2加氢为甲烷的研究,2019.01~2020.12,5万,在研,主持

3.2017年广西壮族自治区科技计划,2017AC05012,LED驱动电容用高比容铝箔化成技术的研发与应用,2018.01-2020.12,30万,在研,主持.

4.广西自然科学基金杰出青年基金,2016GXNSFFA380015,二氧化碳多相催化转化与强化,2016.09-2020.08,40万,在研,主持。

5.国家自然科学基金地区基金,21366004,多相催化臭氧选择氧化肉桂醛为苯甲醛的研究,2014.01-2017.12,40万,已结题,主持。

6.国家自然科学基金委员会-广东省政府联合基金(第二期)超级计算科学应用研究专项,多相催化臭氧选择氧化肉桂醛为苯甲醛的研究,2016.01-2016.12,1.75万,已结题,主持。

7.国家自然科学基金项目青年基金,21006013,等离子体活化耦合多相催化二氧化碳合成二甲醚的研究,2011.01~2013.12,19万,已结题,主持。

8.2016年广西石化资源加工及过程强化技术重点实验室主任基金, 2016Z003, 二维TiO2/MXenes的制备及其光催化二氧化碳为低碳烃的研究, 2017.01~2018.12, 5万,在研,主持。

9.广西石化资源加工及过程强化技术重点实验室开放课题,2015K004,光催化还原二氧化碳为低碳烃的研究,2016.01~2017.12,3万,已结题,主持。

10.2015年度广西壮族自治区高等学校科研项目,KY2015ZL002,等离子体活化二氧化碳催化加氢过程的研究,2015.01~2016.12,1万元,已结题,主持。

11.广西石化资源加工及过程强化技术重点实验室开放课题,2013K012,等离子体协同光催化还原二氧化碳的研究,2013.10~2015.07,2万,已结题,主持。

12.南宁化工股份有限公司(横向课题),三氯乙醛废硫酸净化技术开发,2013.07-2014.08,4万元,已结题,主持。

13.广西林产化学与工程重点实验室开放课题,GXFC12-08,过渡金属氧化物多相催化臭氧选择氧化醛类的效能与机理,2013.01-2014.12,2万,已结题,主持。

14.岳阳湘渝焦糖实业有限公司(横向课题),焦糖色的生产与研发,2011.11-2012.10,2.75万元,已结题,主持。

15.广西大学科研基金项目,XBZ090780,含钇复合氧化物的制备及其可见光催化降解有机废水的研究,2009.11-2011.11,1.2万,已结题,主持。

16.广西研究生教育创新计划,2008105930817D004,具有可见光响应的新型含铋双金属含氧酸盐光催化剂的研究,2008.08-2009.08,2.4万,已结题,主持。

参加项目:

1.广西自然科学基金重点项目,2015GXNSFDA139005,构筑淀粉基吸附材料分离苯乙酮和1-苯乙醇,2015.09-2018.08,30万,在研,参与(第二)。

2.The Nanoscience Research User Program at the Center for Nanophase Materials Sciences (CNMS), Ork Ridge National Laboratory,CNMS2016-243,BiYO3-based Photocatalysts for Hydrocarbons Production from Carbon Dioxide Reduction,2016/08-2017/07,10万美元,在研,参加(第三)。

3.广西自然科学基金,2014GXNSFAA118049,Ni-NiO膨润土层柱状多孔材料的构筑及其催化加氢性能,2014.06-2017.05,5万元,在研,参与(排名第二)

4.国家自然科学基金地区基金,21166002,天然多组分体系中极性不饱和物质的π-配位萃取研究,2012.01-2015.12,50万,已结题,参与(第二)。

指导本科生创新实验项目

[1] 广西大学2010年“大学生创新性实验计划”校级项目:钼基催化剂的制备及其催化选择氧化对二甲苯为对苯二甲醛的研(201017),负责人:黄艳秋(工艺082班)

[2] 广西大学大学生实验技能和科技创新能力训练基金项目:三氯乙醛废硫酸净化技术开发(SYJN20120342),负责人:何诚(工艺104班)

[3] 广西大学大学生实验技能和科技创新能力训练基金项目: 催化臭氧氧化肉桂醛为苯甲醛的研究(SYJN20130355),负责人:韩琦(工艺114班)

[4] 广西大学“大学生创新创业训练计划”项目:Y/TiO2光催化CO2还原的反应过程研究(201411),负责人:吴彩莹(工艺121班)

[5] 2015年自治区级大学生创新创业训练计划项目: 液相等离子体强化光催化二氧化碳还原(201510593205),负责人:黄荣荣(工艺131班)

学术成果

Book Section

[3] Qin Z*, Su T, Ji H*. Chapter 13. Photocatalytic nanomaterials for the energy and environmental application[A]. Z. Guo, Y. Chen, and N. Lu. Multifunctional Nanocomposites for Energy and Environmental Applications[C]. John Wiley & Sons, Inc., pp. 353-401, 2018.01.

[2] Qin Z*, Zhou Y, Jiang Y, Liu Z*, Ji H*. Chater 4. Recent Advances of Heterogeneous Catalytic Hydrogenation of CO2 to Methane[A]. M. T. Ravanchi. New Advances in Hydrogenation Processes - Fundamentals and Applications[C]. Rijeka, Croatia: InTech, 2017. 57-82.

[1] Qin Z-z*, Su T-m, Ji H-b*, Jiang Y-x. Chapter 2: Photocatalytic Reduction of Carbon Dioxide[A]. E. Lichtfouse, J. Schwarzbauer, and D. Robert. Environmental Chemistry for a Sustainable World[C]. Springer International Publishing, 2015.61-98.

Journal articles

2020年

[43] Qin Z, Chen J, Xie X, Luo X, Su T*, Ji H*. CO2 reforming of CH4 to syngas over nickel‑based catalysts[J]. Environmental Chemistry Letters, 2020, doi: 10.1007/s10311-020-00996-w.

2019年

[42] Qin Z, Wang X, Dong L, Su T, Li B, Zhou Y, Jiang Y, Luo X, Ji H*. CO2 methanation on Co/TiO2 catalyst: effects of Y on the support[J]. Chemical Engineering Science, 2019, 210: 115245.

[41] Du P, Su T, Luo X, Xie X, Qin Z*, Ji H. Zr-Modified ZnO for the Selective Oxidation of Cinnamaldehyde to Benzaldehyde[J]. Catalysts, 2019, 9(9): 716.

[40] Su T, Qin Z*, Ji H, Wu Z*. An overview of photocatalysis facilitated by 2D heterojunctions[J]. Nanotechnology, 2019, 30(50): 502002.

[39] Su T*, Hood Z D, Naguib M, Bai L, Luo S, Rouleau C M, Ivanov I N, Ji H, Qin Z*, Wu Z*. Monolayer Ti3C2Tx as an Effective Co-catalyst for Enhanced Photocatalytic Hydrogen Production over TiO2[J]. ACS Applied Energy Materials, 2019, 2(7): 4640-4651.(Front cover)

[38] Su T*, Hood Z D, Naguib M, Bai L, Luo S, Rouleau C M, Ivanov I N, Ji H, Qin Z*, Wu Z*. 2D/2D Heterojunction of Ti3C2/g-C3N4 nanosheets for Enhanced Photocatalytic Hydrogen Evolution[J]. Nanoscale, 2019,11(17): 8138-8149.(Front cover, ESI高被引论文)

[37] Xie X, Huang J, Zhang Y*, Tong Z, Liao A, Guo X, Qin Z*, Guo Z*. Aminated cassava residue-based magnetic microspheres for Pb(II) adsorption from wastewater[J]. Korean Journal of Chemical Engineering, 2019, 36(2): 226-235.

2018年

[36] Jiang Y, Huang T, Dong L, Su T, Li B, Luo X, Xie X*, Qin Z*, Xu C, Ji H. Mn Modified Ni/Bentonite for CO2 Methanation[J]. Catalysts, 2018, 8(12): 646.

[35] Yi Y, Zhang P, Qin Z, Yu C, Li W, Qin Q, Li B, Fan M, Liang X, Dong L. Low temperature CO oxidation catalysed by flower-like Ni-Co-O: how physicochemical properties influence catalytic performance[J]. RSC Advances, 2018, 8(13): 7110-7122.

[34] Qian J, Hou X, Qin Z, Li B, Tong Z, Dong L, Dong L. Enhanced catalytic properties of Cu-based composites for NOx reduction with coexistence and intergrowth effect[J]. Fuel, 2018, 234: 296-304.

[33] Ma R, Dong L, Li B, Su T, Luo X*, Qin Z*, Ji H. g-C3N4/BiYO3 Composite for Photocatalytic Hydrogen Evolution[J]. ChemistrySelect, 2018, 3(21): 5891-5899.

[32] Du P, Su T, Luo X*, Zhou X, Qin Z*, Ji H, Chen J. Bi-, Y-codoped TiO2 for carbon dioxide photocatalytic reduction to formic acid under visible light irradiation[J]. Chin. J. Chem., 2018, 36(6): 538-544.

[31] Jiang Y, Huang T, Dong L, Qin Z*, Ji H*. Ni/bentonite catalysts prepared by solution combustion method for low-temperature CO2 methanation[J]. Chin. J. Chem. Eng., 2018, 26(11): 2361-2367.

[30] Su T, Shao Q, Qin Z*, Guo Z*, Wu Z*. Role of Interfaces in Two-Dimensional Photocatalyst for Water Splitting[J]. ACS Catalysis, 2018, 8(3): 2253-2276.(ESI热点论文、高被引论文)

[29] Su T, Peng R, Hood Z D, Naguib M, Ivanov I N, Keum J K, Qin Z*, Guo Z*, Wu Z*. One-step Synthesis of Nb2O5/C/Nb2C (MXene) Composites and Their Use as Photocatalysts for Hydrogen Evolution[J]. ChemSusChem, 2018, 11(4):688-699.(ESI高被引论文)

[28] Jiang Y, Li X, Qin Z*, Ji H*. Acid treated bentonite supported Ni catalysts by rapid microwaves assisted drying for nitrobenzene hydrogenation[J]. Chemical Engineering Communications, 2018, 205(5): 624-636.

[27] Zhou Y, Su T, Jiang Y, Xie X, Xie Q, Qin Z*, Ji H*. Influence of Zr, Ce, and La on Co3O4 catalyst for CO2 methanation at low temperature[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 768-774.

[26] Jiang Y, Huang T, Xu Y, Li X, Qin Z*, Ji H. Anti-Coke Properties of Acid-Treated Bentonite-Supported Nickel-Boron Catalyst[J]. Chemical Engineering & Technology, 2018, 41(1): 175-181.

[25] 周郁文, 苏通明, 蒋月秀, 秦祖赠*, 纪红兵*. Co负载量对Co/TiO2催化剂CO2甲烷化性能的影响[J]. 精细化工, 2018, 35(1): 72-80.

2017年

[24] Xie X, Xiong H, Zhang Y*, Tong Z, Liao A, Qin Z*. Preparation magnetic cassava residue microspheres and its application for Cu(II) adsorption[J]. Journal of Environmental Chemical Engineering, 2017, 5(3): 2800-2806.

[23] Wu J, Su T, Jiang Y, Xie X, Qin Z*, Ji H*. Catalytic ozonation of cinnamaldehyde to benzaldehyde over CaO: Experiments and Intrinsic kinetics[J]. AICHE Journal, 2017, 63(10): 4403-4417.

[22] Wu J, Su T, Jiang Y, Xie X, Qin Z*, Ji H*. In situ DRIFTS study of O3 adsorption on CaO, γ-Al2O3, CuO, α-Fe2O3 and ZnO at room temperature for the catalytic ozonation of cinnamaldehyde[J]. Applied Surface Science, 2017, 412: 290-305.

[21] 徐云, 蒋月秀*, 秦祖赠*, 纪红兵. Ni-P非晶态合金/酸化膨润土的制备及加氢性能[J]. 化工进展, 2017, 36(5): 1719-1726.

[20] Su T, Tian H, Qin Z*, Ji H*. Preparation and characterization of Cu modified BiYO3 for carbon dioxide reduction to formic acid[J]. Applied Catalysis B: Environmental, 2017: 202: 364-373.

[19] Su T, Zhou X, Qin Z*, Ji H*. Intrinsic Kinetics for Dimethyl Ether Synthesis from Plasma Activation CO2 Hydrogenation over Cu-Fe-Ce/HZSM-5[J]. ChemPhysChem, 2017, 18(3): 299-309.

2016年

[18] Xia H, Liu Z*, Xu Y, Zuo J, Qin Z*. Highly Efficient V-Mo-Fe-O Catalysts for Selective Oxidation of Toluene to Benzaldehyde[J]. Catalysis Communications, 2016, 86: 72-76.

[17] Liu Z*, Li Y, Huang X, Zuo J, Qin Z*, Xu C. Preparation and Characterization of Ni-B/SiO2sol Amorphous Catalyst and Its Catalytic Activity for Hydrogenation of Nitrobenzene[J]. Catalysis Communications, 2016, 85: 17-21.

[16] Zhou X, Su T, Jiang Y, Qin Z*, Ji H, Guo Z*. CuO-Fe2O3-CeO2/HZSM-5 Bifunctional Catalyst Hydrogenated CO2 for Enhanced Dimethyl Ether Synthesis [J]. Chemical Engineering Science, 2016, 153: 10-20.

[15] Qin Z*, Tian H, Su T, Ji H, Guo Z*. Soft Template Inducted Hydrothermal BiYO3 Catalyst for Enhanced Formic Acid Formation from Photocatalytic Reduction of Carbon Dioxide[J]. RSC Advances, 2016, 6(58): 52665-52673.

[14] Jiang Y-x, Li X-l, Qin Z-z*, Ji H-b*. Preparation of Ni/bentonite catalyst and its applications in the catalytic hydrogenation of nitrobenzene to aniline[J]. Chinese Journal of Chemical Engineering, 2016, 24(9): 1195-1200.

[13] Su T, Qin Z*, Huang G, Ji H*, Jiang Y, Chen J. Density functional theory study on the interaction of CO2 with Fe3O4(111) surface[J]. Applied Surface Science, 2016, 378: 270-276.

[12] Qin Z-z*, Zhou X-h, Su T-m, Jiang Y-x, Ji H-b*. Hydrogenation of CO2 to Dimethyl Ether on La-, Ce-Modified Cu-Fe/HZSM-5 Catalysts[J]. Catalysis Communications, 2016, 75: 78-82.

[11] Su T-m, Qin Z-z*, Ji H-b*, Jiang Y-x, Huang G. Recent advances in the photocatalytic reduction of carbon dioxide[J]. Environmental Chemistry Letters, 2016, 14(1): 99-112.

2015年

[10] Qin Z-z*, Su T-m, Ji H-b*, Jiang Y-x, Liu R-w, Chen J-h. Experimental and theoretical study of the intrinsic kinetics for dimethyl ether synthesis from CO2 over Cu-Fe-Zr/HZSM-5[J]. AICHE Journal, 2015, 61(5): 1613-1627.

[9] Jiang Y-x, Su T-m, Qin Z-z*, Huang G*. A zinc sulfide-supported iron tetrakis (4-carboxyl phenyl) porphyrin catalyst for aerobic oxidation of cyclohexane[J]. RSC Advances, 2015, 5(31): 24788-24794.

2014年

[8] Qin Z-z, Liu Z-l*, Wang Y-h. Promotion Effect of Mo on Amorphous Ni-P Catalyst for Liquid-phase Nitrobenzene Catalytic Hydrogenation to Aniline[J]. Chemical Engineering Communications, 2014, 201(3): 338-351.

[7] Qin Z-z*, Su T-m, Jiang Y-x, Ji H-b*, Qin W-g. Preparation of W-modified Fe-Mo catalyst and its applications in the selective oxidization of p-xylene to terephthalaldehyde[J]. Chemical Engineering Journal, 2014, 242: 414-421.

[6] Su T-m, Qin Z-z*, Ji H-b, Jiang Y-x. Preparation, Characterization, and Activity of Y2O3-ZnO Complex Oxides for the Photodegradation of 2,4-Dinitrophenol[J]. International Journal of Photoenergy, 2014, 2014: 794057.

2013年

[5] Liu R-w, Qin Z-z*, Ji H-b*, Su T-m. Synthesis of Dimethyl Ether from CO2 and H2 Using a Cu-Fe-Zr/HZSM-5 Catalyst System[J]. Industrial & Engineering Chemistry Research, 2013, 52(47): 16648-16655.

2012年

[4] Su T-m, Liu Z-l, Liang Y, Qin Z-z*, Liu J, Huang Y-q. Preparation of PbYO Composite Photocatalysts for Degradation of Methyl Orange under Visiblelight Irradiation[J]. Catalysis Communications, 2012, 18: 93-97.

2011年

[3] Qin Z-z, Liang Y, Liu Z-l*, Jiang W-q. Preparation of InYO3 catalyst and its application in photodegradation of molasses fermentation wastewater[J]. Journal of Environmental Sciences, 2011, 23(7): 1219-1224.

2009年

[2] Qin Z-z, Liu Z-l*, Liu Y-b, Yang K-d. Synthesis of BiYO3 for degradation of organic compounds under visible light irradiation[J]. Catalysis Communications, 2009, 10(12): 1604-1608.

[1] Qin Z-z, Liu Z-l*, Zeng Y-f, Sun J-h, Yang K-d. The effects of different methods of catalyst preparation on the hydro-electric plasma TiO2-catalyzed degradation of 2,4-dinitrophenol[J]. Environmental Chemistry Letters, 2009, 7(2): 149-153.

授权专利

[1] 秦祖赠, 刘杰, 王锦文, 曾玉凤, 刘自力. 一种天然苯甲醛的制备方法[P]: 中国. 201210008659.2, 2012-01-12.

[2] 秦祖赠, 刘瑞雯, 苏通明, 范闽光, 刘自力. 一种等离子体活化二氧化碳制备二甲醚的方法[P]: 中国. ZL 201210543522.7, 2012.12.14.

[3] 秦祖赠, 刘瑞雯, 苏通明, 范闽光, 刘自力. 一种用于二氧化碳合成二甲醚的催化剂的制备及应用[P]: 中国. ZL 201210568038.X, 2012.12.25.

[4] 秦祖赠, 苏通明, 刘杰, 范有圆, 曾玉凤, 刘自力. 一种天然苯甲醛的制备方法[P]: 中国. 201210228246.5, 2012-07-03.

[5] 秦祖赠, 苏通明, 刘瑞雯, 李立硕, 刘自力. 一种等离子体活化二氧化碳制备二甲醚的装置[P]: 中国. ZL 201220693781.3, 2012.12.14.

[6] 蒋月秀, 刘瑞雯, 秦祖赠. 一种硝基苯催化加氢合成苯胺的方法[P]: 中国. ZL 201312046633.6, 2013-06-20.

[7] 秦祖赠, 蒋月秀, 苏通明. 一种用于硝基苯催化加氢合成苯胺的催化剂的制备方法[P]: 中国. CN103272601B, 2013-06-20.

[8] 纪红兵, 秦祖赠. 一种苯甲醛的制备方法[P]: 中国. ZL 201410588447.5, 2014-10-28.

[9] 秦祖赠, 苏通明, 田会, 蒋月秀, 纪红兵. 一种二氧化碳还原的方法[P]: 中国. ZL 201410705647.4, 2014-11-26.

[10] 秦祖赠, 覃卫国, 陈军, 龙锋. 一种三氯乙醛废硫酸净化的方法[P]: 中国. 201410814176.0, 2014-12-23.

[11] 秦祖赠, 覃卫国, 陈军, 龙锋. 一种三氯乙醛废硫酸净化的装置[P]: 中国. CN 204417379 U, 2014-12-23.

[12] 秦祖赠, 周新辉, 蒋月秀, 苏通明, 纪红兵, 李立硕. 一种二甲醚的制备方法[P]: 中国. 201410704876.4, 2014-11-26.

[13] 秦祖赠, 韩琦, 苏通明, 纪红兵. 一种连续催化臭氧氧化肉桂醛为苯甲醛的制备方法[P]: 中国. ZL 201510132197.9, 2015-03-25.

[14] 蒋月秀, 栗西亮, 秦祖赠, 王雯. 一种硝基苯催化加氢催化剂的制备方法[P]: 中国. ZL 201410750860.7, 2014-12-09.

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